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Catalysis of the breakage of a carbon-oxygen bond. Catalysis of the cleavage of a carbon-oxygen bond by elimination of a phosphate. Catalysis of the reaction: farnesyl diphosphate = (-)-E-beta-caryophyllene + diphosphate. Catalysis of the conversion of geranyl diphosphate (GPP) into the cyclic monoterpene sabinene. Catalysis of the reaction: 2-trans,6-trans-farnesyl diphosphate = pentalenene + diphosphate. Catalysis of the reaction: geranylgeranyl diphosphate = casbene + diphosphate. Catalysis of the reaction: (E,E,E)-geranylgeranyl diphosphate + H2O = (E,E)-geranyllinalool + diphosphate. Catalysis of the reaction: H2O + geranyl-PP = pyrophosphate + sabinene hydrate. Catalysis of the reaction: geranyl diphosphate = (+)-(4R)-limonene + diphosphate. Catalysis of the reaction: trans,trans-farnesyl diphosphate = pyrophosphate + (+)-delta-cadinene. Catalysis of the reaction: farnesyl diphosphate = alpha-humulene + diphosphate. Catalyzing the formation of cyclic terpenes through the cyclization of linear terpenes containing varying quantities of isoprene units (i.e. isopentenyl-PP, geranyl-PP, farnesyl-PP and geranylgeranyl-PP). Catalysis of the reaction: geranyl diphosphate = (E)-beta-ocimene + diphosphate. Catalysis of the reaction: geranyl diphosphate = pinene + diphosphate. Catalysis of the reaction: 6-[(1S,2R)-1,2-dihydroxy-3-triphosphooxypropyl]-7,8-dihydropterin = 6-pyruvoyl-5,6,7,8-tetrahydropterin + triphosphate. Catalysis of the reaction: trans,trans-farnesyl diphosphate = aristolochene + diphosphate. Catalysis of the reaction: (+)-copalyl diphosphate = (-)-abietadiene + diphosphate. Catalysis of the reaction: ent-copalyl diphosphate = ent-isokaurene + diphosphate. Catalysis of the reaction: trans,trans-farnesyl diphosphate = trichodiene + diphosphate. Catalysis of the reaction: geranylgeranyl diphosphate = taxa-4,11-diene + diphosphate. Catalysis of the reaction: ent-copalyl diphosphate = ent- pimara-8(14),15-diene + diphosphate. Catalysis of the reaction: geranyl diphosphate = limonene + diphosphate. Catalysis of the reaction: syn-copalyl diphosphate = stemod-13(17)-ene + diphosphate. Catalysis of the reaction: geranyl diphosphate = myrcene + diphosphate. Catalysis of the reaction: ethanolamine phosphate + H2O = acetaldehyde + NH3 + phosphate. Catalysis of the reaction: ent-copalyl diphosphate = ent-sandaracopimaradiene + diphosphate. Catalysis of the reaction: 3-deoxy-arabino-heptulosonate 7-phosphate = 3-dehydroquinate + phosphate. Catalysis of the reaction: H2O + geranyl-PP = pyrophosphate + (-)-endo-fenchol. Catalysis of the cleavage of C-C, C-O, C-N and other bonds by other means than by hydrolysis or oxidation, or conversely adding a group to a double bond. They differ from other enzymes in that two substrates are involved in one reaction direction, but only one in the other direction. When acting on the single substrate, a molecule is eliminated and this generates either a new double bond or a new ring. Catalysis of the reaction: trans,trans-farnesyl diphosphate = vetispiradiene + diphosphate. Catalysis of the reactions: 2-trans,6-trans-farnesyl diphosphate + H2O = (1E,4S,5E,7R)-germacra-1(10),5-dien-11-ol + diphosphate and 2-trans,6-trans-farnesyl diphosphate = (-)-(7S)-germacrene D + diphosphate. Catalysis of the reaction: 2-trans,6-trans-farnesyl diphosphate = (+)-(R)-germacrene A + diphosphate. Catalysis of the reaction: 2-trans,6-trans-farnesyl diphosphate = amorpha-4,11-diene + diphosphate. Catalysis of the reaction: geranyl diphosphate + H2O = (3S)-linalool + diphosphate. Catalysis of the reaction: geranyl diphosphate + H2O = (3R)-linalool + diphosphate. Catalysis of the reaction: dimethylallyl diphosphate = isoprene + diphosphate. Catalysis of the reaction: ent-copalyl diphosphate = ent-kaurene + diphosphate. Catalysis of the reaction: 5-O-(1-carboxyvinyl)-3-phosphoshikimate = chorismate + phosphate. Catalysis of the removal of the phosphate group from phosphothreonine by cleavage of the C-OP bond with the concomitant abstraction of the alpha proton, generating a double bond-containing product. Catalysis of the reaction: ent-copalyl diphosphate = ent-cassa-12,15-diene + diphosphate. Catalysis of the reaction: (+)-syn-copalyl diphosphate = (-)-9-beta-pimara-7,15-diene + diphosphate. Catalysis of the reaction: glycerone phosphate = methylglyoxal + phosphate. Catalysis of the reaction: O-phospho-L-homoserine + H2O = L-threonine + phosphate. Catalysis of the reaction: (+)-syn-copalyl diphosphate = stemar-13-ene + diphosphate.

View Gene Ontology (GO) Term

GO TERM SUMMARY
Name: carbon-oxygen lyase activity, acting on phosphates
Acc: GO:0016838
Aspect: Molecular Function
Desc: Catalysis of the cleavage of a carbon-oxygen bond by elimination of a phosphate.
Proteins in PDR annotated with:
   This term: 2 [Search]
   Term or descendants: 85 [Search]


[geneontology.org]
INTERACTIVE GO GRAPH

GO:0016838 - carbon-oxygen lyase activity, acting on phosphates (interactive image map)
YRC Informatics Platform - Version 3.0
Created and Maintained by: Michael Riffle