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Catalysis of the reaction: 3-methyl-2-oxobutanoate + lipoamide = S-(2-methylpropanoyl)dihydrolipoamide + CO2. Catalysis of an oxidation-reduction (redox) reaction in which an aldehyde or ketone (oxo) group acts as a hydrogen or electron donor and reduces a hydrogen or electron acceptor. Catalysis of an oxidation-reduction (redox) reaction, a reversible chemical reaction in which the oxidation state of an atom or atoms within a molecule is altered. One substrate acts as a hydrogen or electron donor and becomes oxidized, while the other acts as hydrogen or electron acceptor and becomes reduced. Catalysis of an oxidation-reduction (redox) reaction in which an aldehyde or ketone (oxo) group acts as a hydrogen or electron donor and reduces a disulfide. Catalysis of the reaction: pyruvate + lipoamide = S-acetyldihydrolipoamide + CO2. Catalysis of the reaction: 2-oxoglutarate + lipoamide = S-succinyldihydrolipoamide + CO2.

View Gene Ontology (GO) Term

GO TERM SUMMARY

Name: oxidoreductase activity, acting on the aldehyde or oxo group of donors, disulfide as acceptor
Acc: GO:0016624
Aspect: Molecular Function
Desc: Catalysis of an oxidation-reduction (redox) reaction in which an aldehyde or ketone (oxo) group acts as a hydrogen or electron donor and reduces a disulfide.
Synonyms:
  • oxidoreductase activity, acting on the aldehyde or oxo group of donors, disulphide as acceptor
Proteins in PDR annotated with:
   This term: 24 [Search]
   Term or descendants: 112 [Search]


[geneontology.org]
INTERACTIVE GO GRAPH

GO:0016624 - oxidoreductase activity, acting on the aldehyde or oxo group of donors, disulfide as acceptor (interactive image map)

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